First year mechanisms   Second year mechanisms   Third year mechanisms: Deprecated: mysql_connect(): The mysql extension is deprecated and will be removed in the future: use mysqli or PDO instead in /home/orie1876/public_html/ORGMECH/category.php on line 123       Free Radicals       Option one       Pericyclic Reactions       Stereoselectivity       Synthesis       Transition metal chemistry   All mechanisms   Books

Deprecated: mysql_connect(): The mysql extension is deprecated and will be removed in the future: use mysqli or PDO instead in /home/orie1876/public_html/ORGMECH/category.php on line 176 Stereoselectivity Mechanisms Displaying 35 mechanisms: Stereoselectivity and mechanism- Asymmetric synthesis- Stereocontrol of ester enolate formation Stereoselectivity and mechanism- Asymmetric synthesis- Stereocontrol of ketone enolate formation Stereoselectivity and mechanism- Asymmetric synthesis- Stereoselecitivty of enolate with aldehdye (Zimmerman-Traxler) Stereoselectivity and mechanism- Asymmetric synthesis- Stereoselecitivty using boron enolates Stereoselectivity and mechanism- Hammett equation- Non-linear- SN1 reaction Stereoselectivity and mechanism- Acid-base catalysis- epoxide opening Stereoselectivity and mechanism- Acid-base catalysis- hydrolysis with intramolecular proton transfer Stereoselectivity and mechanism- Acid-base catalysis- intramolecular proton transfer Stereoselectivity and mechanism- Addition to alkenes- Asymmetric epoxidation using bleach and manganese macrocycle Stereoselectivity and mechanism- Addition to alkenes- Electrophile mediated cyclisation- cascade Stereoselectivity and mechanism- Addition to alkenes- Ene mediated cyclisation Stereoselectivity and mechanism- Addition to alkenes- Epoxidation- hydrogen bonding control Stereoselectivity and mechanism- Addition to alkenes- AcOH and I2 (Prevost Woodward reaction) Stereoselectivity and mechanism- Addition to alkenes- Sharpless epoxidation Stereoselectivity and mechanism- Addition to alkenes- Simmons-Smith cyclopropanation- chelation control Stereoselectivity and mechanism- Addition to carbonyls- Aldol reaction Stereoselectivity and mechanism- Addition to carbonyls- Asymmetric reduction Stereoselectivity and mechanism- Addition to carbonyls- Asymmetric reduction- chiral catalyst Stereoselectivity and mechanism- Addition to carbonyls- Asymmetric reduction- liver alcohol dehydrogenase Stereoselectivity and mechanism- Addition to carbonyls- Chelation control Stereoselectivity and mechanism- Addition to carbonyls- Felkin-Anh model Stereoselectivity and mechanism- Addition to carbonyls- Felkin-Anh model Stereoselectivity and mechanism- Addition to carbonyls- Felkin-Anh model with electronegative group Stereoselectivity and mechanism- Gauche effect with dioxane Stereoselectivity and mechanism- Hammett equation- Amide formation Stereoselectivity and mechanism- Hammett equation- Non-linear- acyl chloride hydrolysis Stereoselectivity and mechanism- Hammett equation- Non-linear- change in RDS Stereoselectivity and mechanism- Hammett equation- Non-linear- change in RDS- imine formation Stereoselectivity and mechanism- Hammett equation- Non-linear- Neighbouring group participation Stereoselectivity and mechanism- Hammett equation- SN1 reaction Stereoselectivity and mechanism- Hammett equation- SN2 reaction Stereoselectivity and mechanism- lone pair acceleration of hydrolysis Stereoselectivity and mechanism- lone pair acceleration of hydrolysis- 1,3-allylic strain Stereoselectivity and mechanism- lone pair acceleration of hydrolysis- kinetic vs. thermodynamic Stereoselectivity and mechanism- Pyranose lone pair acceleration of hydrolysis